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Question

To which of the following mixtures Dalton's law is not applicable?

A
CO2 and CO at room temperature
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B
Ammonia and hydrogen chloride at room temperature
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C
NH3 and steam at room temperature
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D
He and H2
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Solution

The correct options are
C NH3 and steam at room temperature
D Ammonia and hydrogen chloride at room temperature
Dalton's Law of Partial Pressure, and it states that the pressure of a gas mixture is the sum of the partial pressures of the individual components of the gas mixture.
Ammonia and hydrogen chloride at room temperature and NH3 and steam at room temperature react with each other.
So Dalton's law is not applicable Ammonia and hydrogen chloride at room temperature and NH3 and steam at room temperature.
Hence options B & C are correct.

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