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Question

Toluene, when treated with Br2/FeCl3 gives p-bromotoluene as the major product because the CH3 group:

A
is ortho-para directing
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B
is meta directing
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C
deactivates the ring
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D
None of the above
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Solution

The correct option is A is ortho-para directing
The above reaction is electrophillic substitution reaction, in which methyl group is ring activating and ortho-para directing group. Hence, both ortho and p-bromotoluene will be formed but para is major product here.
Hence, the correct answer is option (a).

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