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Byju's Answer
Standard XII
Chemistry
Tautomerism
Trans-2 - phe...
Question
Trans-2 - phenyl -1 - bromocyclopentane on reaction with alcoholic KOH produces:
A
4 - Phenyl cyclo pentene
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B
2 - Phenyl cycio pentene
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C
1 - Phenyl cyclo pentene
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D
3 - Phenyl cyclo pentene
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Solution
The correct option is
D
3 - Phenyl cyclo pentene
Trnas-2-phenyl-1-Bromo cyclo pentane
Structure is as follows :
halo alloane treatment with dlcoholic
K
O
H
results in
E
2
anti-elimination mechanism
Anti elimination means
H
and
B
r
both departing groups must be present at dihedral angle
180
0
(anti).
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0
Similar questions
Q.
Reaction of trans-2-Phenyl-1-bromocyclopentane on reaction with alcoholic
K
O
H
produces
Q.
Reaction of
t
r
a
n
s
−
2
−
p
h
e
n
y
l
−
1
−
b
r
o
m
o
c
y
c
l
o
p
e
n
t
a
n
e
on reaction with alcoholic
K
O
H
produces (major):
Q.
When
1
−
pentene is treated with an acid,
t
r
a
n
s
−
2
−
pentene is produced. Propose mechanism of this isomerization reaction and justify.
Q.
The product formed on the reaction of chloroform with aniline and alcoholic
K
O
H
is:
Q.
Standard state Gibbs energy changes for the isomerization reaction.
c
i
s
−
2
−
p
e
n
t
e
n
e
→
t
r
a
n
s
−
2
−
p
e
n
t
e
n
e
i
s
−
3.67
k
J
/
m
o
l
a
t
400
K
.
If more trans-2-pentene is added to the reaction vessel, then:
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