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pH of Salts

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Treatment of compound $O$ with $K M n O_{4} / H^{+}$ gave $P$ , which on heating with ammonia gave $Q$ . The compound $Q$ on treatment with $B r_{2} / N a O H$ produced $R$ . On strong heating, $Q$ gave $S$ , which on further treatment with ethyl $2 -$ bromopropanoate in the presence of $K O H$ followed by acidification, gave a compound $T$
.

A

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B

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C

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D

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Solution

The correct option is C

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Q. Treatment of compound O with

K M n O_{4} / H^{+}

gave P, which on heating with ammonia gave Q. The compound Q on treatment with

B r_{2} / N a O H

produced R. On strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in the presence of

K O H

followed by acidification, gave a compound T.

The compound T is:

Q. Treatment of compound O with

K M n O_{4} / H^{+}

gave P, which on heating with ammonia gave Q. The compound Q on treatment with

B r_{2} / N a O H

produced R. On strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in the presence of

K O H

followed by acidification, gave a compound T.

The compound T is:

Given compound (A) upon treatment with

K M n O_{4} / H^{+}

gives (B), which on heating with ammonia produces (C). (C) on treatment with

B r_{2} / N a O H

produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of

K O H

followed by acidification gives (F).

(D) is:

Given compound (A) upon treatment with

K M n O_{4} / H^{+}

gives (B), which on heating with ammonia produces (C). (C) on treatment with

B r_{2} / N a O H

produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of

K O H

followed by acidification gives (F).

(F) from the following is:

Q. An organic compound (A) on reducing gave a compound (B). Upon treatment with

{H N O}_{3}

, (B) gave ethyl alcohol and on warming with

{C H C l}_{3}

and alcoholic KOH. (B) gave an offensive smell. The compound (A) is

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