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Question

Treatment of nitrobenzene with acetyl chloride in the presence of anhydrous AlCl3 gives :

A
2-nitroacetophenone
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B
3-nitroacetophenone
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C
4-nitroacetophenone
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D
none of the above
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Solution

The correct option is D none of the above
NO2 group being a powerful electron withdrawing group reduces the electron density over the benzene ring or deactivates the nucleus towards electrophilic aromatic substitution reaction and it fails to undergo Friedel-Crafts reaction.

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