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Question

Two chamber containing m1 and m2 grams of a gas at pressure P1 and P2 respectively are put in communication with each other, temperature remaining constant. The common pressure reached will be.

A
P1P2(m1+m2)P2m1+P1m2
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B
P1P2m1P2m1+P1m2
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C
m1m2(P1+P2)P2m1+P1m2
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D
m1m2P2P2m1+P1m2
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Solution

The correct option is C P1P2(m1+m2)P2m1+P1m2
According to Boyle's law, PV=kT(a constant)
or Pmρ=kT or ρ=PmkT

or ρ=PK (where kTm=K a constant)

So, ρ1=P1K and V1=m1ρ1=m1P1/K=Km1P1
Similarly, V2=Km2P2
Total volume =V1+V2=K(m1P1+m2P2)

Let P be the common pressure and ρ be the common density of mixture. Then.
ρ=m1+m2V1+V2=m1+m2K(m1P1+m2P2)

P=Kρ=m1+m2m1P1+m2P2=P1P2(m1+m2)(m1P2+m2P1)

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