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Question

Two chambers, one containing m1g of a gas at P1 pressure and other containing m2g of a gas at P2 pressure are put in communication with each other. If temperature remains constant, the common pressure reached will be:

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Solution

PV=nRT
P1V1=n1RT
V1=m1MRTP1
M= Molecule wt at gas.
T= Common temperature.
V2=m2MRTP2
V1+V2=(m+m1)MRTPeff=Veff
m1P1+m2P2=m1+m2Peff
Peff=(m1+m2)P1P2P2m1+P1m2

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