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Question

Two closed bulbs of equal volumes (V) containing an ideal gas initially at pressure pi and temperature T1 are
connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one of the bulbs is then raised to T2. The final pressure pf is:

A
2pi(T1T1+T2)
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B
2pi(T2T1+T2)
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C
2pi(T1T2T1+T2)
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D
pi(T1T2T1+T2)
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Solution

The correct option is B 2pi(T2T1+T2)
Initial total moles:

n=piVRT1+piVRT1=2piVRT1(1)

Final total moles:

n=pfVRT1+pfVRT2(2)

Equating the two:

2piT1=pfT1+pfT2

pf=2piT1×T1T2(T1+T2)

pf=2pi×T2(T1+T2)

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