Two different bond lengths are observed in PF5 molecule but only one bond length is observed in SF6.
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Solution
PCl5 has trigonal bipyramidal structure in which bond angles of 90∘ and 120∘ exist. Hence, two types of bond length are observed, axial bonds are longer than the equatorial bonds while in case of SF6, there is only one type of angle (90∘) and has octahedral structure.