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Question

Two different liquids of same mass are kept in two identical vessels, which are placed in a freezer that extracts heat from them at the same rate causing each liquid to transform into a solid. The schematic figure shows the temperature T vs time t plot for the two material. We denote the specific heat of materials in the liquid(solid) states to be CL1(CS1) and CL2(CS2) respectively. Choose the correct option.
739322_baa7ed780e9040029a6b9d203ad98753.png

A
CL1<CL2 and CS1<CS2
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B
CL1>CL2 and CS1<CS2
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C
CL1>CL2 and CS1>CS2
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D
CL1<CL2 and CS1>CS2
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Solution

The correct option is B CL1>CL2 and CS1<CS2
Clearly, initial slopes show the temperature change in the solid state. As in 1st curve, there is a large change in temperature in the same time interval compared to that of 2nd curve i.e slope of 1 is larger so cS1<cS2.
Similarly, slope of curve 2 is larger in the later part of the graph hence, cL1<cL2

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