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Question

Two elements X and Y are starting elements of 3rd and 4th periods. One with lower density is:

A
X
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B
Y
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C
both have same
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D
none of these
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Solution

The correct option is B Y
3rd and 4th periods start with sodium and potassium is less than that of sodium. This is because sodium has no vacant d subshell and is small in size. Though an increase in nuclear charge from 11 to 19 increases mass increase in atomic volume is more than that of atomic mass. Since density is mass per unit volume, it decreases.

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