Two equal vectors have a resultant equal to either of them, then the angle between them will be
Applying the formula:
R2=P2+Q2+2PQcosα
P2=P2+P2+2PPcosα
=2P2+2P2cosα=2P2(1+cosα)
1+cosα=12
⇒2cos2α2=12
⇒cos2α2=14
⇒cosα2=12=cos60o
⇒α2=60o⇒α=120o