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Question

Two Faraday of electricity is passed through a solution of CuSO4. The mass of copper deposited at the cathode is:

(At. mass of Cu = 63.5 amu)

A
0 g
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B
63.5 g
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C
2 g
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D
127 g
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Solution

The correct option is B 63.5 g
Cu2++2eCu.
From the above-given half-reaction, two moles of electrons react with one mole of Cu(II) to deposit one mole of Cu. This corresponds to 63.5 g (molecular weight) of copper.

Two Faraday's of electricity corresponds to 2 moles of electrons. Hence, they will deposit 63.5 g of copper.

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