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Question

Two flasks I and II shown below are connected by a valve of negligible volume.


When the valve is openend, the final pressure of the system in bar is x×102. The value of x is _____.
(Integer answer)
[Assume - ideal gas: 1 bar=105 Pa.
Molar mass of N2=28.0 g mol1 R=8.31 J mol1 K1

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Solution

Number of moles of flask I=2.828=0.1
Number of moles of flask II=0.228=1140
Assuming the system attains a final temperature of T
Heat lost by N2 of flask I = Heat gained by N2 of flask II
nICm(300T)=nIICm(T60)
0.1(300T)=1140(T60)
Final temperatureT=284 K
PT=n1RTV1=(110+1140) mol×8.31 J mol1 K1×284 K3×103 m3×105barPa=84.2
PT=84.28×102barx=84 (nearest integer)

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