Let P be the force of 5 kg weight and Q be the force of 10 kg weight.
By parallelogram law of vector addition, the resultant is,
R2=P2+Q2+2PQcosθ
R2=25+100+100cos120∘
R=5√3weight
Let α be the angle made by R with 10 kg weight.
tanα=PsinθP+Qcosθ
tanα=5sin1205+10cos120
tanα=1√3
α=30∘