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Question

Two glass bulbs A (of 100 ml capacity), and B (of 150 ml capacity) containing same gas are connected by a small tube of negligible volume. At particular temperature the pressure in A was found to be 20 times more that that in bulb B. The stopcock is opened without changing the temperature. The pressure in A will?

A
drop by 75%
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B
drop 57%
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C
drop by 25%
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D
will remain same
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Solution

The correct option is B drop 57%
Let the original pressure in B be P.
Pressure in A = 20 P.

Given that :

Volume in A = 100 mL
Volume in B = 150 mL

After opening the stopcock,
total volume =(100+150)mL=250mL

According to Boyle's law :

PfVf=PiVi

Let the partial pressure of gas in A be PA :

PA×250=100×20P

PA=100×20P250=8P

Let Partial pressure of gas in B be PB :

PB×250=150×P

PB=150P250=0.6P

Total pressure =8P+0.6P=8.6P

Now,

Drop in pressure in A =20P8.6P=11.4P

% drop in pressure =11.4P20P×100=57%

Hence, the correct option is A

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