Two identical containers A and B with frictionless pistons contain the same ideal gas at the same temperature and the same volume V. The mass of the gas in A is mA and that in B is mB The gas in each cylinder is now allowed to expand isothermally to the same final volume 2V. The changes in the pressure in A and B are found to be △P and 1.5 △P respectively. Then
Process is isothermal. There fore, T = constant, (P∝1V) volume is increasing, therefore pressure will decreases
In Chamber A :
△P=Pi−Pf=μARTV−μART2V=μART2V ------------(i)
In Chamber B :
1.5△P=Pi−Pf=μBRTV−μBRT2V=μBRT2V ------------(ii)
from equations (i) and (ii) μAμB=11.5=23
⇒mAMmBM=23⇒3mA=2mB.