Two metal rods A, B are dipped in their ionic solutions respectively. Following reaction occurs at each electrode:
A→A2++2e−B2++2e−→B
Which rod will acquire negative charge?
A
What we constructed is electrochemical cell.
The electrode melts into the electrolytic solution as A2+ ions leaving electrons on the rod A since A→A2++2e−
So rod A, where oxidation reaction happens, will acquire negative charge because of e- released during oxidation reaction.