Dear Student ,
Let the charge q flow from bigger sphere to smaller sphere .For them to have same potential we can write that ,
( q-0.01) /1 = (0.05-q) /3
solving we get , q = 0.02 C
So hence the charge on the bigger sphere is = 0.05 - q = 0.03 C = 3 x 10-2 c
Regards