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Question

Two moles of an ideal gas is changed from its initial state (16atm,6L) to final state (4atm,15L) in such a way that this change can be represented by a straight line in P−V curve. The maximum temperature attained by the gas during the above change is:

(Take R=112 L atm K−1 mol−1)

A
324K
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B
604K
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C
1296K
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D
9782K
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Solution

The correct option is D 604K
Given P1=16 atm
P2=4 atm
V1=6 L
V2=15 L
The shaded portion of the above graph represents the work done
Area=area of the triangle= ABC+Area of rectagleBCED
=12×9×12+9×4=90LAtm=W
W=2.303×nRTlogV2V1-
90=2.303×2×0.083×T×log156
T=604 K

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