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Question

Two moles of helium gas (γ=5/3) are initially at a temperature of 27oC and occupy a volume of 20 litres. The gas is first expanded at constant pressure until the volume is doubled. It then undergoes an adiabatic change until the temperature returns to its initial value.
What are the final volume and pressure of the gas?

A
PC=1.44×105N/m2,VC=113.1 litre.
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B
PC=0.44×105N/m2,VC=113.1 litre.
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C
PC=0.44×105N/m2,VC=213.1 litre.
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D
PC=0.44×106N/m2,VC=113.1 litre.
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Solution

The correct option is B PC=0.44×105N/m2,VC=113.1 litre.
No of moles =2
r=53
T2=300 K(27+273=300 k)
V=20 ltr
Vf=40 ltr
in constant pressure VTi=Vf1Tf1Tf1=600 k
in adiabatic process
TVr1=k
Tf1Vf1=Ti(Vf)r1
(600)(40)2/3=(300)(Vf)2/3
(23/2)(40)=Vf
Solve & we get
Vf=113.1 ltr
for Pf use eqn of state
nR=PiViTi=PfVfTf (Tf=Ti)
Pi(20)=(113.1)Pf
2×(23)×(300)=Pf((113.1)1000) 1 ltr=m31000 R=8.3 Jk1mol1
44,031.8302=Pf
Pf=0.44×105N/m2

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