Momentum(P) is the product of mass and velocity.
In first case,
mass =2m
velocity =2v
momentum (Pa) =2m*2v=4mv.
In second case,
mass =3m
velocity =v
momentum (Pb) = 3m*v = 3mv.
there for the ratio of momentum
Pa / Pb = 4mv / 3mv = 4/3
Ratio of their momentum
= 4/3