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Question

Two platinum electrodes were immersed in a solution of CuSO4 and current was passed through the solution. After sometime it was found that colour of CuSO4 disappeared with the evolution of gas at the electrode. The colourless solution contains:


A
platinum sulphate
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B
copper sulphate
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C
copper hydroxide
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D
sulphuric acid
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Solution

The correct option is B sulphuric acid
SO24 oxidises less readily as compared to OH
at anode O2 is released and
SO24 ions remain is solution
whereas the copper ion having higher reduction potential then H+ will get reduced more easily then H+
and at cathode Cu++eCu (metal).
Sulphate ion and hydrogen ion combine to form sulphuric acid.
SO24 + 2H+ H2SO4

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