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Question

Two radioactive compounds A and B have half lives equal to 40 hrs and 24 hrs respectively. If initial concentrations of A and B are equal then after X hours the concentration of B will be half of the concentration of A. The value of X10 is

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Solution

Radioactive decay follow 1st order kinetics
ln([A]t[A]0)=λAt ...(i)
ln([B]t[B]0)=λBt ...(ii)
[A]0=[B]0 and[A]t=2[B]t
(i)(ii)
ln2=t(λBλA)=t(ln224ln240)
t=24×4016=60hr=X

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