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Question

Two rigid boxes containing different ideal gases are placed on a table. Box A contains one mole of nitrogen at temperature T0, while box B contains one mole of helium at temperature (73)T0. The boxes are then put into thermal contact with each other, and heat flows between them until the gases reach a common final temperature (Ignore the heat capacity of boxes). Then, the final temperature of the gases, Tf in terms of T0 is -

A
Tf=37T0
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B
Tf=73T0
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C
Tf=32T0
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D
Tf=52T0
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Solution

The correct option is C Tf=32T0
Here, change in internal energy of the system is zero, i.e increase in internal energy of one is equal to decrease in internal energy of other.
ΔU=nCvΔT
where n=Number of mole
Cv for N2=52
Cv for He=32

ΔUA=1×5R2×(TfT0)
ΔUB=1×3R2(Tf73T0)
Now, ΔUA+ΔUB=0
put the values,
5R2(TfT0)+3R2(Tf73T0)=0
5R2Tf5RT02+3RTf23R×72×3T0=0
5R2Tf+3RTf2=7R2T0+5RT02
8R2Tf=12R2T0=6RT0
Tf=32T0

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