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Question

Two solutions of non-volatile solutes A and B having molar mass ratio of A and B (MA/MB) as 1/3 are prepared by dissolving 5% (mass/vol.) of each in water.
Calculate the ratio of freezing point depression.

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Solution

(MA/MB)=1/3
Also ΔTf=Kb×m
Hence, ΔTA/ΔTB=mA/mB=MB/MA=3/1

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