Two spherical vessel of equal volume, are connected by a n arrow tube. The apparatus contains an ideal gas at one atmosphere and 300K. Now if one vessel is immersed in a bath of constant temperature 600K and the other in a bath of constant temperature 300K. Then the common pressure will be
μ = μ1 + μ2
P(2V)RT1 = P′VRT1+P′VRT2 ⇒ 2PRT1 = P′R[T2+T1T1T2]
P′ = 2PT2(T1+T2) = 2×1×600(300+600) = 43atm