Two moles of an ideal monoatomic gas at 27∘C occupies a volume of V. If the gas is expanded adiabatically to the volume 23/2V, then the work done by the gas will be (γ=53,R=8.31J/mol K)
A
3739.5J
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B
2627.23J
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C
2500J
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D
−2500J
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Solution
The correct option is A3739.5J Given, gas is monoatomic ∴γ=53 Initial Temperature (Ti)=300K Initial volume (Vi)=V Final volume (Vf)=23/2V Work done by the gas (W)=nR(Ti−Tf)γ−1 =nRTiγ−1[1−TfTi] As, TiVγ−1i=TfVγ−1f ∴W=nRTiγ−1[1−(ViVf)γ−1] =2×8.31×300(53−1)⎡⎢
⎢⎣1−(123/2)23⎤⎥
⎥⎦ =3739.5J