Two thermally insulated vessels 1 and 2 are filled with air at temperature (T1,T2), volume (V1,V2) and pressure (P1,P2) respectively. If the valve joining the two vessels is opened, the temperature inside the vessel at equilibrium will be:
A
T1+T2
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B
(T1+T2)/2
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C
T1T2(P1V1+P2V2)P1V1T2+P2V2T1
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D
T1T2(P1V1+P2V2)P1V1T1+P2V2T2
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Solution
The correct option is CT1T2(P1V1+P2V2)P1V1T2+P2V2T1 As there is no loss of energy the initial energy is going to be equal to final energy , average kinetic energy per molecule is 32KT
n1=P1V1T1n2=P2V2T2
initial KE = 32n1KT1+32n2KT2
final KE = 32(n1+n2)KT
So intial KE = final KE
we get T = n1T1+n2T2n1+n2=P1V1+P2V2P1V1T1+P2V2T2=T1T2(P1V1+P2V2)P1V1T2+P2V2T1