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Question

Two thermally insulated vessels 1 and 2 are filled with air at temperature (T1,T2), volumes (V1,V2) and pressure (P1,P2) respectively. If the value joining the two vessels is opened, the temperature inside the vessel at equilibrium will be (P = common pressure)

A
T1+T2
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B
(T1+T2)/2
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C
T1T2P(V1+V2)P1V1T2+P2V2T1
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D
T1T2(P1V1+P2V2)P1V1T2+P2V2T1
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Solution

The correct option is C T1T2P(V1+V2)P1V1T2+P2V2T1
From ideal gas law,
P1V1=n1RT1
P2V2=n2RT2
Since the total mass of the gas remains same before and after the vessels are joined,
n1+n2=n
P1V1RT1+P2V2RT2=P(V1+V2)RT
T=T1T2P(V1+V2)P1V1T2+P2V2T1

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