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Question

Two types of FXF angles are present in which of the following molecule? (X=S, Xe, C)

A
SF4
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B
XeF4
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C
SF6
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D
CF4
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Solution

The correct option is A SF4
In SF4, S is sp3d hybridized one equatorial position is occupied by a lone pair which repels the axial bond pairs thereby decreasing the angle from 180 to 173. The other angle between FSF is 102.

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