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Question

Two vessels A and B of eual volume V0 are connected by a narrow tube which can be closed by a valve. The vessels are fitted with pistions whi ch can be moved to change the volumes. Initially, the valve is open and the vessels contain an ideal gas (Cp/Cv=γ) at atmospheric pres sure P0 and atmospheric temperature T0. The walls of the vessels A are diathermic and those of B are adiabatic. The valve is now clo sed and the pistons are slowely pulled out to incr ease the volumes of the vessels to double the original value.

(a) Find the temperatures and pressures in the two vessels.

(b) The valve is now opened for suffiecient time so that the gases acquire a common temperature and pressure. Find the new values of the temper ature and the pressure.

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Solution

Initial pressure = P0

Initial temperature = T0

Initial volume = V0CPCv=γ

(a) For diathermic vessel the temperature inside remains constant.

P1V1=P2V2

P0V0=P2×V2

P2=P02

Temperature = T0

For adiabatic vessels the temperature does not remain constant. The process is adiabatic

T1Vγ11=T2Vγ12

ToVγ1o=T×(2Vo)γ1

T2=To×2γ1

P1Vγ1=P2Vγ2

PoVγo=P2×(2Vo)γ

P2=(Po2γ)

(b) When the valves are open, the temperature remains To through out

P1=P2 and T1=T1=To

So, Po=P1+P2

= 2P1=2P2

So, P1=P2=Po2


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