Photolysis of water: Occurs at grana i.e., lumen side of grana thylakoid membrane with the help of water splitting complex or OEC (oxygen evolving complex). This step is associated with PS- II of Z- scheme.
2H2O→4H++O2+4e−
2 water molecules produce 4 protons. So, twelve water will produce 24 protons.
Hence, the correct answer is '24H+'.