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Question

Two weak monobasic organic acids HA and HB have dissociation constants as 1.5×105 and 1.8×105 respectively at 25C. If 500 ml of 1M solution of each of these two two acids are mixed to produce 1 litre of mixed solution, what is the pH of the resulting solution?

A
2.2
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B
2.4
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C
2.6
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D
2.5
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Solution

The correct option is B 2.4
H3O+=C1K1+C2K2=0.5×1.5×105+0.52×105
=16.5×106=4.1×103
pH=log[4.1×103]=2.4

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