Type of isomerism exhibited by $[C r (N C S) {(N H_{3})}_{5}] [Z n C l_{4}]$ is :

coordination isomerism.

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linkage isomerism.

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ionization isomerism.

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both coordination and linkage isomerism.

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Solution

The correct option is D both coordination and linkage isomerism.
As -NCS and -SCN are isomer, both acts as ligand here, so linkage isomer due to this.
Also in this Cl and NCS can change coordinate sphere so coordination ismerism due to this.

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Q. The type of isomerism shown by the complex

[C o C l_{2} (e n)_{2}]

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[C r (N O_{2}) (N H_{3})_{5}] [Z n C l_{4}]

:
(I) IUPAC name of compound is pentaamminenitrito-N-chromium (III) tetrachlorozincate(II)
(II) It shows geometrical isomerism
(III) It shows linkage isomerism
(IV) It shows coordination isomerism.

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What kind of isomerism exists between $[C r (H_{2} O)_{6}] C l_{3} (v i o l e t)$ and $[C r (H_{2} O)_{5} C l] C l_{2} . H_{2} O (g r e y i s h - g r e e n)$ ?
(a) Linkage isomerism
(b) Solvate isomerism
(c) Ionisation isomerism
(d) Coordination isomerism

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Type of isomerism exhibited by [Cr(NCS)(NH3)5][ZnCl4] is :

The correct option is D both coordination and linkage isomerism.As -NCS and -SCN are isomer, both acts as ligand here, so linkage isomer due to this.Also in this Cl and NCS can change coordinate sphere so coordination ismerism due to this.

Type of isomerism exhibited by $[C r (N C S) {(N H_{3})}_{5}] [Z n C l_{4}]$ is :

The correct option is D both coordination and linkage isomerism.
As -NCS and -SCN are isomer, both acts as ligand here, so linkage isomer due to this.
Also in this Cl and NCS can change coordinate sphere so coordination ismerism due to this.