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Question

Under hydrolytic conditions, the compounds used in the preparation of linear polymer and for chain termination respectively, are

A
CH3SiCl3 and Si(CH3)4
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B
(CH3)2SiCl2 and (CH3)3SiCl
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C
(CH3)2SiCl2 and CH3SiCl3
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D
SiCl4 and (CH3)3SiCl
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Solution

The correct option is B (CH3)2SiCl2 and (CH3)3SiCl
Me2SiCl2 on hydrolysis forms linear polymer. In the presence of Me3SiCl the polymerisation reaction is terminated.

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