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Question

Under what conditions does ethane get converted to :
(a) ethyl alcohol, (b) acetaldehyde,
(c) acetic acid.

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Solution

a) Ethane reaction with chlorine in presence of sunlight to give chloroethane.
reaction of chloroethane with alkoholic KOH to give ethanol.
C2H6+Cl2 CH3CH2Cl
C2H6+alcoholicKOH CH3CH2OH

(b) When mixture of ethane and oxygen is passed through heated molybdenum oxide, the mixture is oxidized to Acetaldehyde.
C2H6+O2 CH3CHO+H2O | In presence of MoO

(c)Ethanol formed from ethane gets oxidized to acetic acid.
2C2H6+O2 2C2H5OH |at 120 atm in presence of cu tubes at 475 K
C2H5OH+O2 CH3COOH+H2O |Pt at 300 C


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