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Question

Under which of the following conditions, a real gas shows maximum deviation from the ideal behaviour?

A
100oC and 2 atm P
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B
0oC and 2 atm P
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C
100oC and 5 atm P
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D
500oC and 5 atm P
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Solution

The correct option is C 100oC and 5 atm P
Under the conditions 100oC and 5 atm P, a real gas shows maximum deviation from the ideal behavior.

At lowest temperature and highest pressure, the compressibility factor z, has high value.

z=PVnRT
Higher is the value of z, higher is the deviation from ideal behavior.
Hence, option C is correct.

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