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Question

2CuSO4–––––––+4KICu2I2+2K2SO4+I2
The equivalent weight of the underlined compound by taking its molecular weight as M is :

A
E=M
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B
E=M3
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C
E=M2
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D
none of these
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Solution

The correct option is A E=M
The oxidation number of Cu in CuSO4 is 2.
The oxidation number of Cu in Cu2I2 is 1.
Thus, the oxidation number of Cu changes by 1.
Equivalent weight=Molecular weightChange in the oxidation number
Hence, E=M1

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