3MnO2–––––––––+6KOH+KClO3⟶3K2MnO4+KCl+3H2O The equivalent weight of the underlined species by taking its molecular weight as M is :
A
E=M
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B
E=M3
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C
E=M6
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D
E=M2
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Solution
The correct option is DE=M2 The oxidation number of Mn in MnO2 is +4. The oxidation number of Mn in K2MnO4 is +6. Thus, the oxidation number of Mn changes by 2. Equivalent weight=Molecular weightChange in the oxidation number Hence, E=M2