Unit mass of a liquid with volume V1 is completely changed into a gas of volume V2 at a constant external pressure P and temperature T. If the latent heat of evaporation for the given mass is L, then the increase in the internal energy of the system is
△Q=△U+P△V⇒mL=△U+P(V2−V1)
⇒△U=L−P(V2−V1) (∵m=1)