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Standard XII
Chemistry
Ammonia
Upon treatmen...
Question
Upon treatment with ammoniacal
H
2
S
, the metal ion solutions that precipitates as sulphide is ________.
1. Fe(III)
2. Zn(II)
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Solution
Z
n
2
+
will give zinc sulphide, upon treating with ammonical
H
2
S
.
i.e.
Z
n
2
+
+
H
2
S
→
Z
n
S
+
2
H
+
where as
A
l
3
+
and
F
e
3
+
from respective hydroxide and
M
g
2
+
from respective bicarbonate upon treating with ammonical
H
2
S
.
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Similar questions
Q.
Upon treatment with ammoniacal
H
2
S
, the metal ion that precipitates as a sulfide is:
Q.
Upon treatment with ammonical
H
2
S
, the metal ion that precipitates as a sulphide is:
Q.
Assertion :
S
b
(
I
I
I
)
is not precipitated as sulphide when in its alkaline solution
H
2
S
is passed. Reason: Concentration of
S
2
−
ions in alkaline medium is inadequate for precipitation.
Q.
The best way to ensure complete precipitation of a metal sulphide
M
S
from saturated
H
2
S
(
a
q
)
with a metal ion
M
2
+
is by :
Q.
Assertion :When
H
2
S
gas is passed into an aqueous solution of
Z
n
C
l
2
,
Z
n
2
+
ions are completely precipitated as zinc sulphide. Reason: Zinc sulphide is insoluble in solutions of caustic alkali but dissolves in dilute
H
C
I
.
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