Use the following data to answer the question below.
Calculate the resonance energy of anthracene:
A
84 kcal/mol
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B
100 kcal/mol
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C
110 kcal/mol
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D
116 kcal/mol
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Solution
The correct option is A 84 kcal/mol Resonance energy = Theoretical heat of hydrogenation – Experimental heat of hydrogenation.
So theoretical heat of hydrogenation (H.O.H.) for anthracene is
Theoretical ΔH=7×(–28.6)=–200.2 kcal/mol
Experimental ΔH=–116.2 kcal/mol
Resonance energy = 84 kcal/mol