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Standard XII

Chemistry

Central Atom and Ligands

Using IUPAC n...

Question

Using IUPAC norms write the systematic names of the following:
(i) $[C o (N H_{3})_{6}] C l_{3}$ (ii) $[P t (N H_{3})_{2} C l (N H_{2} C H_{3})] C l$ (iii) $[T i (H_{2} O)_{6}]^{3 +}$ (iv) $[C o (N H_{3})_{4} C l (N O_{2}] C l$ (v) $[M n (H_{2} O)_{6}]^{2 +}$ (vi) $[N i C l_{4}]^{2 -}$ (vii) $[N i (N H_{3})_{6}] C l_{2}$ (viii) $[C o (e n)_{3}]^{3 +}$ (ix) $[N i (C O)_{4}]$

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Solution

(i) Hexaamminecobalt(III)chloride
(ii) Diamminechloridomethylamineplatinum(II)chloride
(iii) Hexaaquatitanium(III)ion
(iv) Tetraamminechloridonitrito-N-cobalt(III)chloride
(v) Hexaaquamanganese(II)ion
(vi) Tetrachloridonickelte(II)ion
(vii)Hexaamminenickel(II)chloride
(viii)Tris (ethan-1,2-diamine)cobalt(III)ion
(ix) Tetracarbonylnickel(0)

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Similar questions

Using IUPAC norms write the systematic names of the following:
(i) $[C o {(N H_{3})}_{6}] C l_{3}$

(ii) $[P t {(N H_{3})}_{2} C l (N H_{2} C H_{3})] C l$

(iii) ${[T i {(H_{2} O)}_{6}]}_{6}^{3 +}$

(iv) ${[M n {(H_{2} O)}_{6}]}_{6}^{2 +}$

(v) ${[N i C l_{4}]}_{4}^{2 -}$

(vi) $[N i {(N H_{3})}_{6}] C l_{2}$

(vii) ${[C o {(e n)}_{3}]}_{3}^{3 +}$

(viii) $[N i {(C O)}_{4}]$

Write the IUPAC names of the following coordination compounds:

(i) [Co(NH₃)₆]Cl₃

(ii) [Co(NH₃)₅Cl]Cl₂

(iii) K₃[Fe(CN)₆]

(iv) K₃[Fe(C₂O₄)₃]

(v) K₂[PdCl₄]

(vi) [Pt(NH₃)₂Cl(NH₂CH₃)]Cl

Using IUPAC norms write the formulae of the following:
(i) Tetrahydroxozincate (II)

(ii) Potassium tetrachloropalladate (II)

(iii) Diamminedichlorido platinum (II)

(iv) Potassium tetracyanonickelate (II)

(v) Pentaamminenitro-O-cobalt (III)

(vi) Hexaamminecobalt (III) sulphate

(vii) Potassiumtri(oxalato) chromate (III)

(viii) Hexaammineplatinum (IV)

(ix) Tetrabromidocuprate (II)

(x) Pentaamminenitrito-N-cobalt (III)

Q. Using IUPAC norms write the formulas for the following:

(i) Tetrahydroxidozincate(II)
(ii) Potassium tetrachloridopalladate(II)

(iii) Diamminedichloridoplatinum(II)

(iv) Potassium tetracyanidonickelate(II)
(v) Pentaamminenitrito-O-cobalt(III)
(vi) Hexaamminecobalt(III) sulphate
(vii) Potassium tri(oxalato)chromate(III)
(viii) Hexaammineplatinum(IV)
(ix) Tetrabromidocuprate(II)
(x) Pentaamminenitrito-N-cobalt(III)

Q. (i) Write the IUPAC name of the complex

[C r {(N H_{3})}_{4} {C l}_{2}] C l

.
(ii) What type of isomerism is exhibited by the complex

{[C o {(e n)}_{3}]}^{3 +}

?
(

e n =

ethane-1, 2-diamine)
(iii) Why is

{[N i {C l}_{4}]}^{2 -}

paramagnetic but

[N i {(C O)}_{4}]

is diamagnetic?
(

C r = 24, C o = 27, N i = 28

)

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Using IUPAC norms write the systematic names of the following:(i) [Co(NH3)6]Cl3 (ii) [Pt(NH3)2Cl(NH2CH3)]Cl (iii) [Ti(H2O)6]3+ (iv) [Co(NH3)4Cl(NO2]Cl (v) [Mn(H2O)6]2+ (vi) [NiCl4]2− (vii) [Ni(NH3)6]Cl2 (viii) [Co(en)3]3+ (ix) [Ni(CO)4]