Using IUPAC norms write the systematic names of the following-i - Co NH 36- Cl 3ii - Pt N H 32 Cl N H 2 CH 3- Cliii - Ti i H 2 O 6-3-iv - Mn H 2 O 6-2-v - NiCl 4-2-vi -Ni - NH 36- Cl 2vii -Co en -3- -viii - Ni CO 4-

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Standard XII

Chemistry

Nomenclature of Coordination Compounds

Using IUPAC n...

Question

Using IUPAC norms write the systematic names of the following:
(i) $[C o {(N H_{3})}_{6}] C l_{3}$

(ii) $[P t {(N H_{3})}_{2} C l (N H_{2} C H_{3})] C l$

(iii) ${[T i {(H_{2} O)}_{6}]}_{6}^{3 +}$

(iv) ${[M n {(H_{2} O)}_{6}]}_{6}^{2 +}$

(v) ${[N i C l_{4}]}_{4}^{2 -}$

(vi) $[N i {(N H_{3})}_{6}] C l_{2}$

(vii) ${[C o {(e n)}_{3}]}_{3}^{3 +}$

(viii) $[N i {(C O)}_{4}]$

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Solution

(i) Hexamminnecobalt (III) chloride.

(ii) Diamminechlorido (methyl amine) platinum (II) chloride.

(iii) Hexaaquatitanium (III) ion.

(iv) Hexaaquamanganese (II) ion.

(v) Tetrachloridonickelate (II) ion.

(vi) Hexaammine nickel (II) chloride.

(vii) Trix-(ethane-1,2-diamine) cobalt (III) ion.

(viii) Tetracarbonyl nickel.

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Using IUPAC norms write the systematic names of the following:

(i) [Co(NH₃)6]Cl₃

(ii) [Pt(NH₃)₂Cl(NH₂CH₃)]Cl

(iii) [Ti(H₂O)6]³⁺

(iv) [Co(NH₃)₄Cl(NO₂)]Cl

(v) [Mn(H₂O)6]²⁺

(vi) [NiCl₄]²⁻

(vii) [Ni(NH₃)₆]Cl₂

(viii) [Co(en)₃]³⁺

(ix) [Ni(CO)₄]

Write the IUPAC names of the following coordination compounds:

(i) [Co(NH₃)₆]Cl₃

(ii) [Co(NH₃)₅Cl]Cl₂

(iii) K₃[Fe(CN)₆]

(iv) K₃[Fe(C₂O₄)₃]

(v) K₂[PdCl₄]

(vi) [Pt(NH₃)₂Cl(NH₂CH₃)]Cl

Q. Using IUPAC norms, write the systematic names of the following.
(i)

K_{4} [F e (C N)_{6}]

(ii)

[C u (N H_{3})_{4}] S O_{4}

Q. (i) Write the IUPAC name of the complex

[C r {(N H_{3})}_{4} {C l}_{2}] C l

.
(ii) What type of isomerism is exhibited by the complex

{[C o {(e n)}_{3}]}^{3 +}

?
(

e n =

ethane-1, 2-diamine)
(iii) Why is

{[N i {C l}_{4}]}^{2 -}

paramagnetic but

[N i {(C O)}_{4}]

is diamagnetic?
(

C r = 24, C o = 27, N i = 28

)

Q. (i) Write the IUPAC name of the complex

[C r (N H_{3})_{4} C l_{2}] C l

.
(ii) What type of isomerism is exhibited by the complex

[C o (e n)_{3}]^{3 +}

?
(en= ethane-1,2-diamine)
(iii) Why is

[N i C l_{4}]^{2 -}

paramagnetic but

[N i (C O)_{4}]

is diamagnetic?
(At. Nos. : Cr = 24, Co = 27, Ni = 28)

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Nomenclature of Coordination Compounds

Standard XII Chemistry

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Using IUPAC norms write the systematic names of the following: (i) [Co(NH3)6]Cl3 (ii) [Pt(NH3)2Cl(NH2CH3)]Cl (iii) [Ti(H2O)6]3+ (iv) [Mn(H2O)6]2+ (v) [NiCl4]2− (vi) [Ni(NH3)6]Cl2 (vii) [Co(en)3]3+ (viii) [Ni(CO)4]