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Question

Using the standard electrode potentials given in the table, predict if the reaction between the following is possible.
Fe3+(aq) and I(aq)
423705_ba1b009cb3164ab49fd7c1f5c909426e.jpg

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Solution

The oxidation half reaction is 2I(aq)I2(s)+2e;E0=0.54V.
The reduction half reaction is [Fe3+(aq)+e]×2;E0=+0.77×2 V=+0.77V.
The net cell reaction is 2Fe3+(aq)+2I(aq)2Fe2+(aq)+I2(s);E0=+23V.
Since, the cell potential is positive, the reaction is feasible.

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