Using the standard electrode potentials given in the table, predict if the reaction between the following is possible.
Fe3+(aq) and I−(aq)
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Solution
The oxidation half reaction is 2I−(aq)→I2(s)+2e−;E0=−0.54V. The reduction half reaction is [Fe3+(aq)+e−→]×2;E0=+0.77×2V=+0.77V. The net cell reaction is 2Fe3+(aq)+2I−(aq)→2Fe2+(aq)+I2(s);E0=+23V. Since, the cell potential is positive, the reaction is feasible.