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Question

Using the standard electrode potentials given in the table, predict if the reaction between the following is possible.
Fe3+(aq) and Cu(s)
423708_350b4d6ce97448ca87149f8030f54d2f.jpg

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Solution

Oxidation half reaction is Cu(s)Cu2+(aq)+2e;E0=0.34V.
Reduction half reaction is [Fe3+(aq)+eFe2+(aq)]×2;E0=+0.77V.
The net cell reaction is 2Fe3+(aq)+Cu(s)2Fe2+(aq)+Cu2+;E0=+0.43V.
Since, the cell potential is positive, the reaction is feasible.

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