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Vacuum Distillation is a separation technique that is used to separate a solid that has dissolved in a liquid and made a solution.
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Vacuum distillation is a method of distillation for purifying liquids and separating mixtures of liquids into their individual components whereby the pressure above the liquid mixture to be distilled is reduced to less than its vapor pressure causing evaporation of the most volatile liquid(s) (those with the lowest boiling points).
Crystallization is a separation technique that is used to separate a solid that has dissolved in a liquid to made a solution, in which mass transfer of a solute from the liquid solution to a pure solid crystalline phase occurs.

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