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Question

Value of kf of water is 1.86 k g mole -1 if your vehicles radiator can accommodate 1kg of water then how many grams of ethylene glycol can be dissolved in it so that freezing point of solution becomes -2.8 degree Celsius

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Solution

Normal freezing point of water = 0 degree celsius
Required freezing point = -2.8 degree celsius (given)
Depression in freezing point = 2.8 degrees
Volume of water = 1 kg of water
Kf of water = 1.86 kg mole -1

We have, depression in freezing point
ΔT = iKfm

where m is molality and
i = 1 (ethylene glycol is an organic compound so it does not dissociate in solution and has an i factor of 1)
=> 2.8 = 1*1.86*m
=> m= (2.8)/(1.86)
= 1.5053 g/L

Molality = no of moles of solute / Mass of solvent (in kg)
=> m = 1.5053 = no of moles of ethylene glycol / 1 kg
=> no of moles of ethylene glycol = 1.5053 moles

Mass of ethylene glycol that can be dissolved = no of moles * Molar mass
= 1.5053 * 62
= 93.33 grams

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