The correct option is
D normal molecular massobserved molecular massThe van 't Hoff factor is a measure of the effect of a solute upon colligative properties such as osmotic pressure, relative lowering in vapour pressure, the elevation of boiling point and freezing point depression.
The van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass.
=normal molecular massobserved molecular mass
Hence, the correct option is C.